Abstract
The structural, magnetic, and dielectric properties of Pb3Mn7O15 have been investigated using high-quality single crystals. Pb3Mn7O15 adopts a pseudo-hexagonal orthorhombic structure, with partially filled Kagomé layers connected by ribbons of edge-sharing MnO6 octahedra and intercalated Pb cations. There are 9 inequivalent sites in the structure for the Mn ions, which exist both as Mn3+ and Mn4+. Pb3Mn7O15 undergoes an antiferromagnetic transition below TN ~ 67 K, with significant geometric frustration. Neutron powder diffraction on crushed single crystals allowed us to determine the low-temperature antiferromagnetic magnetic structure. We discuss the magnetic interaction pathways in the structure and possible interplay between the structural distortions imprinted by the lone-electron pair of Pb2+ cations and Mn3+/Mn4+ charge ordering.
Cite
CITATION STYLE
Ivanov, S. A., Bush, A. A., Hudl, M., Stash, A. I., André, G., Tellgren, R., … Mathieu, R. (2016). Spin and dipole order in geometrically frustrated mixed-valence manganite Pb3Mn7O15. Journal of Materials Science: Materials in Electronics, 27(12), 12562–12573. https://doi.org/10.1007/s10854-016-5387-3
Register to see more suggestions
Mendeley helps you to discover research relevant for your work.
