Ultrasonic studies of ternary liquid mixtures of N-N-dimethylformamide, nitrobenzene, and cyclohexane at different frequencies at 318 K

Abstract

The ultrasonic velocity, density, and viscosity have been measured for ternary mixtures of nitrobenzene, N,N-dimethylformamide, and cyclohexane at temperature T = 318 K at different frequencies such as 2, 4, 6, and 8 MHz. The experimental data have been used to calculate the acoustical and thermodynamical parameters like adiabatic compressibility, free length, free volume, internal pressure, acoustic impedance, Gibbs free energy, and their excess values. In particular, it is seen that the response of these parameters to frequency is less prominent in comparison to that of the ternary mixtures containing N,N-dimethylformamide, cyclohexane, and chlorobenzene.