Room-temperature deintercalation and self-extrusion of Ga from Cr2GaN

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Abstract

Bulk samples of the layered ternary nitride Cr2GaN were observed to extrude filaments of pure elemental gallium at room temperature. This self- extrusion phenomenon is best described as a room-temperature deintercalation of gallium from the basal planes of porous Cr2GaN samples. The extruded filaments are single crystals with 2- to 100-micrometer diameters and can be several centimeters long.

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Barsoum, M. W., & Farber, L. (1999). Room-temperature deintercalation and self-extrusion of Ga from Cr2GaN. Science, 284(5416), 937–939. https://doi.org/10.1126/science.284.5416.937

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