Abstract
The intramolecular cyclopropanation of various trans-allylic diazoacetates and alkenyl diazoketones has been achieved with excellent enantioselectivities of up to 98% ee and in quantitative yields by using a water-soluble ruthenium(II)/hydroxymethyl(phenyl)oxazoline catalyst in a water/ether biphasic medium. The catalyst could be reused at least five times. © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Author supplied keywords
Cite
CITATION STYLE
Abu-Elfotoh, A. M., Nguyen, D. P. T., Chanthamath, S., Phomkeona, K., Shibatomi, K., & Iwasa, S. (2012). Water-soluble chiral ruthenium(II) phenyloxazoline complex: Reusable and highly enantioselective catalyst for intramolecular cyclopropanation reactions. Advanced Synthesis and Catalysis, 354(18), 3435–3439. https://doi.org/10.1002/adsc.201200508
Register to see more suggestions
Mendeley helps you to discover research relevant for your work.
