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ESI-Mass spectrometry as a tool for investigating the mechanistic role of a 15-membered triolefinic macrocyclic palladium(0) complex in the Heck reaction

Arkivoc (2005) 2005(9) 51-62
DOI: 10.3998/ark.5550190.0006.907
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Abstract

Analysis of organometallic reaction mixtures by ElectroSpray Ionization Mass Spectrometry (ESI-MS) has permitted direct observation of Heck reaction intermediates using a 15-membered triolefinic macrocyclic palladium(0) complex as a recoverable catalyst. Knowledge has been gained of the role of the above- mentioned palladium complex in the Heck reaction by using arenediazonium salts. © ARKAT.

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Pla-Quintana, A., & Roglans, A. (2005). ESI-Mass spectrometry as a tool for investigating the mechanistic role of a 15-membered triolefinic macrocyclic palladium(0) complex in the Heck reaction. Arkivoc, 2005(9), 51–62. https://doi.org/10.3998/ark.5550190.0006.907

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