Effect of Microcapsules on Mechanical, Optical, Self-Healing and Electromagnetic Wave Absorption in Waterborne Wood Paint Coatings

Abstract

A mixture of multiwalled carbon nanotubes (CNTs) and carbonyl iron powder (Iron(0) pentacarbonyl, CIP) was used as a core material, and a melamine-formaldehyde resin was used as a wall material to prepare CIP/CNTs microcapsules. A core-wall ratio, content of CNTs in the core material, stirring speed, and reaction time were carried out to explore the most significant factor affecting the coverage rate and yield of microcapsules. The most important factor affecting the preparation of CIP/CNTs microcapsules was the content of CNTs in the core material. The optimized CIP/CNTs microcapsules were mixed with shellac microcapsules, and the optimal ratio was explored by analyzing their optical, mechanical, and electromagnetic wave absorption properties in order to prepare coatings with superior performance. The lower the addition amount of CIP/CNTs microcapsules, the lower the effect on the color difference of the coating. The gloss and adhesion of waterborne wood paint coatings decreased with increasing CIP/CNTs microcapsule addition. The hardness, impact resistance and tensile properties of the coatings showed a tendency of increasing and then decreasing with the addition of CIP/CNTs microcapsules. The surface roughness of the coating basically tended to increase with the increase of CIP/CNTs microcapsule content. When the content of added CNTs in the core material was 3.0% and the content of microcapsules was 9.0%, the coating had the highest elongation at break of 12.4% and the highest repair rate of 34.3%, respectively. The mixed shellac microcapsules and CIP/CNTs microcapsules achieved a theoretical minimum reflection loss of −13.52 dB at 16.2 GHz, and the electromagnetic wave absorption band of less than −5 dB was 15.3 GHz–18.0 GHz. The results provide technical references for the preparation of self-healing composite electromagnetic wave absorption coatings on wood substrates.