A method for preparing the pH-responsive superhydrophobic paper with high stability

Abstract

In this paper, a simple method for preparing high stability superhydrophobic paper with pH-induced wettability transition was proposed. Firstly, the pH-responsive monomer 2- (dimethylamino) ethyl methacrylate (DMAEMA), the silicon-containing crosslinking monomer 3-trimethoxysilyl propyl methacrylate (TSPM) and the fluorine-containing monomer hexafluorobutyl methacrylate (HFMA) were polymerized to prepare the pH-responsive polymer PHFMA-PTSPM-PDMAEMA. Afterwards, the amino-modified SiO2 was grafted onto the polymer to provide roughness and then coated on the paper to prepare the superhydrophobic paper with pH-responsive properties. Further research found that the modified paper prepared by this method not only has strong stability and transparency, but also can realize the reversible regulation of superhydrophobic & lipophilic and super-oleophobic & hydrophilic properties under different pH-induction, and it has important application value in the field of oil-water separation in industrial applications.