Structural and transport evolution in the LixAg2V4O11 system

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Abstract

We investigated the effect of inserting lithium into Ag2V4O11 (ε-SVO) on the structure, electronic properties and redox committed by combining in situ XRD measurements, ESR spectroscopy and 4 probes DC conductivity coupled with thermopower measurements. The electrochemical discharge occurs in three consecutive steps above 2 V (vs. Li+/Li). The first one, between 0 < x

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Sauvage, F., Bodenez, V., Vezin, H., Morcrette, M., Tarascon, J. M., & Poeppelmeier, K. R. (2010). Structural and transport evolution in the LixAg2V4O11 system. Journal of Power Sources, 195(4), 1195–1201. https://doi.org/10.1016/j.jpowsour.2009.08.091

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