Abstract
Control of the radical polymerization of acrylates, styrene and vinyl acetate has been achieved by using novel dithiocarbamates as reversible addition-fragmentation chain transfer agents. The key parameter for the control with N,N-disubstituted (A) or cyclic (B) dithiocarbamates was found to be the conjugation of the lone pair of electrons of the nitrogen atom with carbonyl or aromatic groups. © WILEY-VCH Verlag GmbH 2000.
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CITATION STYLE
Destarac, M., Charmot, D., Franck, X., & Zard, S. Z. (2000). Dithiocarbamates as universal reversible addition-fragmentation chain transfer agents. Macromolecular Rapid Communications, 21(15), 1035–1039. https://doi.org/10.1002/1521-3927(20001001)21:15<1035::AID-MARC1035>3.0.CO;2-5
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