Rational serendipity: “undirected” synthesis of a large {MnIII10CuII5} complex from pre-formed MnII building blocks

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Abstract

Use of an aminopolyalcohol-based MnII complex in solvothermal CuII chemistry leads to a rare example of a high nuclearity heterometallic {MnIII10CuII5} system, in which four CuII(H1Edte) units trap an inner {MnIII10CuII} oxide core.

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Frost, J. M., Kettles, F. J., Wilson, C., & Murrie, M. (2016). Rational serendipity: “undirected” synthesis of a large {MnIII10CuII5} complex from pre-formed MnII building blocks. Dalton Transactions, 45(45), 18094–18097. https://doi.org/10.1039/c6dt03914f

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