Harnessing the potential of N-heterocyclic carbenes for the rejuvenation of group-transfer polymerization of (meth)acrylics

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Abstract

(Chemical Equation Presented) Neutral but versatile: N-heterocyclic carbenes are very efficient catalysts for the group-transfer polymerization of acrylates and methacrylates in both polar and apolar media. These organocatalysts were also used to design all-(meth)acrylic di-and triblock copolymers. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

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Raynaud, J., Ciolino, A., Baceiredo, A., Destarac, M., Bonnette, F., Kato, T., … Taton, D. (2008). Harnessing the potential of N-heterocyclic carbenes for the rejuvenation of group-transfer polymerization of (meth)acrylics. Angewandte Chemie - International Edition, 47(29), 5390–5393. https://doi.org/10.1002/anie.200800490

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