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A fluorinated cobalt(III) porphyrin complex for hydroalkoxylation of alkynes

Chemical and Pharmaceutical Bulletin (2017) 65(11) 1000-1003
DOI: 10.1248/cpb.c17-00568
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Abstract

A fluorinated cobalt(III) porphyrin complex [Co(TPFPP)-NTf2·2C2H5OH, where TPFPP=5,10,15,20-tetrakis(penta-fluorophenyl)porphyrin, Tf=CF3SO2] promotes hydroalkoxylation of alkynes to give acetals in good to excellent yields. The acetals can be directly functionalized with nucleophiles in a one-pot procedure.

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Ushimaru, R., Nishimura, T., Iwatsuki, T., & Naka, H. (2017). A fluorinated cobalt(III) porphyrin complex for hydroalkoxylation of alkynes. Chemical and Pharmaceutical Bulletin, 65(11), 1000–1003. https://doi.org/10.1248/cpb.c17-00568

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