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Agostic NSi-H⋯Mo complexes: From curiosity to catalysis

Angewandte Chemie - International Edition (2008) 47(40) 7701-7704
DOI: 10.1002/anie.200802147
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Abstract

An uncommon catalyst: The β-agostic NSi-H⋯complex 1 (Ar=2,6-diisopropylphenyl) catalyzes a variety of hydrosilylation reactions. Stoichiometric reactions of 1 with unsaturated compounds proceed via the silanimine intermediate A and, in the case of olefins or nitriles, give products of Si-C coupling, such as 2. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

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Khalimon, A. Y., Simionescu, R., Kuzmina, L. G., Howard, J. A. K., & Nikonov, G. I. (2008). Agostic NSi-H⋯Mo complexes: From curiosity to catalysis. Angewandte Chemie - International Edition, 47(40), 7701–7704. https://doi.org/10.1002/anie.200802147

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