The main group macrocycle [{(4PCH2CH2PAIMe2)2} 4]·4[AIMe3]

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Abstract

Four P4 chains link eight aluminum centers in the [P16Al8] macrocycle [{(PCH2CH2PAlMe2)24 ]·4[AlMe3] (1), which has a unique macrocylic structure comprised solely of main group elements. Compound 1 is produced by the reaction of [AlMe3] (see scheme) with the catalytically produced organotetraphosphane (PCH2CH2PH)2 (2).

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APA

Hoskin, A. J., & Stephan, D. W. (2001). The main group macrocycle [{(4PCH2CH2PAIMe2)2} 4]·4[AIMe3]. Angewandte Chemie - International Edition, 40(10), 1865–1867. https://doi.org/10.1002/1521-3773(20010518)40:10<1865::AID-ANIE1865>3.0.CO;2-7

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