Poly[μ6-(naphthalene-2,6-dicarboxylato)-bis(aqualithium)]

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Abstract

The title compound, [Li2(C12H6O 4)(H2O)2] n , crystallizes with one half of the molecular entities in the asymmetric unit. The second half is gererated by inversion symmetry. The crystal structure has a layered arrangement built from distorted edge-sharing LiO3(OH)2 tetrahedra parallel to (100), with naphthalenedicarboxylate bridging the LiO3(OH) 2 layers along the [100] direction. Hydrogen bonding between the water molecule and adjacent carboxylate groups consolidates the packing.

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Fédèle, L., Sauvage, F., Becuwe, M., & Chotard, J. N. (2014). Poly[μ6-(naphthalene-2,6-dicarboxylato)-bis(aqualithium)]. Acta Crystallographica Section E: Structure Reports Online, 70(8). https://doi.org/10.1107/S1600536814013130

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