Inhomogeneous surface tension of chemically active fluid interfaces

Abstract

We study the dependence of the surface tension of a fluid interface on the density profile of a third suspended phase. By means of an approximated model for the binary mixture and of a perturbative approach, we derive closed-form expressions for the free energy of the system and for the surface tension of the interface. Our results show a remarkable non-monotonous dependence of the surface tension on the spatial separation between the peaks of the density of the suspended phase. Our results also predict the local value of the surface tension in the case in which the density of the suspended phase is not homogeneous along the interface.