Formation and efficient addition of cerium(III) derivative of acetonitrile to ketones

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Abstract

The cerium(III) derivative of acetonitrile undergoes addition with ketones efficiently. It adds effectively to hindered ketones and gives 1,2-adduct exclusively with conjugated enones. © 1991.

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Liu, H. J., & Al-said, N. H. (1991). Formation and efficient addition of cerium(III) derivative of acetonitrile to ketones. Tetrahedron Letters, 32(40), 5473–5476. https://doi.org/10.1016/0040-4039(91)80061-A

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