Enantioselective PCCP Brønsted acid-catalyzed aza-Piancatelli rearrangement

  • Hammersley G
  • Nichol M
  • Steffens H
  • et al.
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Abstract

An enantioselective aza-Piancatelli rearrangement has been developed using a chiral Brønsted acid based on pentacarboxycyclopentadiene (PCCP). This reaction provides rapid access to valuable chiral 4-amino-2-cyclopentenone building blocks from readily available starting material and is operationally simple.

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APA

Hammersley, G. R., Nichol, M. F., Steffens, H. C., Delgado, J. M., Veits, G. K., & Read de Alaniz, J. (2019). Enantioselective PCCP Brønsted acid-catalyzed aza-Piancatelli rearrangement. Beilstein Journal of Organic Chemistry, 15, 1569–1574. https://doi.org/10.3762/bjoc.15.160

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