Research on Hard, Transparent and Hydrophobic Coating on PMMA Sheet

Abstract

Featured Application: This technology can realize self-cleaning of deep-sea optical windows, reducing the cost of equipment maintenance and cleaning. In this paper, nano SiO2 particles modified organic silane coatings were successfully prepared to aim at the application of the self-cleaning coating on PMMA substrate for deep-sea optical windows. The chemicals, surface microstructure, wettability, hardness, adhesion, transparency, water scouring resistance as well as microorganism attachment rate of the coatings were investigated. The results showed that adding SiO2 nanoparticles into the organic silicon coating can effectively improve the hydrophobicity due to generating a micro-nano structure surface. However, excessive addition would result in a decrease in hydrophobicity, adhesion, as well as transparency, due to the inorganic SiO2 particle destroying the integrity of the organic coating. The optimal coating was obtained by adding 0.5 wt% nano SiO2 particles, which possessed a water contact angle of 114.2°, hardness of 4H, adhesion level of 0, and visible light transmittance of 0.886. After 40-h water scouring, the water contact angle decreased to 108.3° and the visible light transmittance decreased to 0.839, suggesting good water scouring resistance. The microorganism attachment rate of the S05 coating was 0.17% after a 6 h immersion test, which was about half that of the PMMA substrate.