5-Methyl-2,4-bis-(methyl-sulfan-yl)tricyclo-[6.2.1.02,7]undeca- 4,9-diene-3,6-dione

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Abstract

The structure analysis of the title compound, C14H 16O2S2, shows the SMe and H atoms of the bond linking the six-membered rings to be syn and also to be syn to the bridgehead CH2- group. Each of the five-membered rings adopts an envelope conformation at the bridgehead CH2- group. The dione-substituted ring adopts a folded conformation about the 1,4-C⋯C vector, with the ketone groups lying to one side. The cyclo-hexene ring adopts a boat conformation.

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Richthofen, A. A. V., Cardoso Filho, J. E. P., Marzorati, L., Zukerman-Schpector, J., Tiekink, E. R. T., & Di Vitta, C. (2010). 5-Methyl-2,4-bis-(methyl-sulfan-yl)tricyclo-[6.2.1.02,7]undeca- 4,9-diene-3,6-dione. Acta Crystallographica Section E: Structure Reports Online, 66(6). https://doi.org/10.1107/S1600536810015710

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