Regioselective prenylation of bromocarbazoles by palladium(0)-catalysed cross coupling-synthesis of O-methylsiamenol, O-methylmicromeline and carquinostatin A

Claudia Thomas; Olga Kataeva; Arndt W. Schmidt; Hans Joachim Knölker

Journal ArticleOPEN ACCESS

Regioselective prenylation of bromocarbazoles by palladium(0)-catalysed cross coupling-synthesis of O-methylsiamenol, O-methylmicromeline and carquinostatin A

Organic and Biomolecular Chemistry (2014) 12(6) 872-875

DOI: 10.1039/c3ob42297f

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Abstract

We describe the regioselective prenylation of 3-bromocarbazole by palladium(0)-catalysed cross coupling with a prenylstannane or a prenylboronate. The procedure is applied to the synthesis of precursors for biologically active carbazole alkaloids. © 2014 The Royal Society of Chemistry.

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Thomas, C., Kataeva, O., Schmidt, A. W., & Knölker, H. J. (2014). Regioselective prenylation of bromocarbazoles by palladium(0)-catalysed cross coupling-synthesis of O-methylsiamenol, O-methylmicromeline and carquinostatin A. Organic and Biomolecular Chemistry, 12(6), 872–875. https://doi.org/10.1039/c3ob42297f

Regioselective prenylation of bromocarbazoles by palladium(0)-catalysed cross coupling-synthesis of O-methylsiamenol, O-methylmicromeline and carquinostatin A

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