Crystal structure of 2-methyl-N-[(4-methylpyridin-2-yl)carbamothioyl]benzamide

Abstract

In the title compound, C15H15N3OS, there is an intramolecular N - H⋯O hydrogen bond and an intramolecular C - H⋯S hydrogen bond involving the C=O and C=S bonds which lie on opposite sides of the molecule. The molecule is non-planar with the benzene and pyridine rings being inclined to one another by 26.86 (9)°. In the crystal, molecules are linked by pairs of N - H⋯S hydrogen bonds, forming inversion dimers with an R22(8) ring motif. The dimers are linked via C - H⋯S hydrogen bonds, forming slabs parallel to the bc plane.