Three-Cation Scandium Borates RxLa1−XSc3(BO3)4(R = Sm, Tb): Synthesis, Structure, Crystal Growth and Luminescent Properties

A. Kokh; A. Kuznetsov; K. Kokh; N. Kononova; V. Shevchenko; B. Uralbekov; A. Bolatov; V. Svetlichnyi

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Three-Cation Scandium Borates RxLa1−XSc3(BO3)4(R = Sm, Tb): Synthesis, Structure, Crystal Growth and Luminescent Properties

Springer Nature, (2019), 267-271

DOI: 10.1007/978-3-030-22974-0_64

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Abstract

Complex ortohoborates of rare earth metals with the general chemical formula RxLa1−xSc3(BO3)4 (R = Sm, Tb) have been obtained by solid state synthesis and spontaneous crystallization. These crystals belong to the huntite family with the space group R32 and for x = 0.5 have unit cell parameters a = 9.823(6), c = 7.975(3) (SLSB) and a = 9.803(3), c = 7.960(4) Å (TLSB).

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Kokh, A., Kuznetsov, A., Kokh, K., Kononova, N., Shevchenko, V., Uralbekov, B., … Svetlichnyi, V. (2019). Three-Cation Scandium Borates RxLa1−XSc3(BO3)4(R = Sm, Tb): Synthesis, Structure, Crystal Growth and Luminescent Properties. In Springer Proceedings in Earth and Environmental Sciences (pp. 267–271). Springer Nature. https://doi.org/10.1007/978-3-030-22974-0_64

Three-Cation Scandium Borates RxLa1−XSc3(BO3)4(R = Sm, Tb): Synthesis, Structure, Crystal Growth and Luminescent Properties

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