Assessment of Some Characteristics and Properties of Zirconium Dioxide Nanoparticles Modified with 3-(Trimethoxysilyl) Propyl Methacrylate Silane Coupling Agent

Abstract

This study presents the results of surface modification of zirconium dioxide (ZrO2) nanoparticles by 3-(trimethoxysilyl) propyl methacrylate silane coupling agent by assessing some characteristics and properties of modified ZrO2 nanoparticles by infrared spectroscopy, thermogravimetric analysis, size distribution, zeta potential, and field emission scanning electron microscopy methods. The modified and unmodified ZrO2 nanoparticles have been used as nanoadditives for organic coatings based on acrylic emulsion resin. The abrasion resistance of acrylic coating was evaluated according to ASTM E968-15. The obtained results show that ZrO2 nanoparticles were functionalized successfully with 3-(trimethoxysilyl) propyl methacrylate silane. The modified ZrO2 nanoparticles exhibit a positive effectiveness in the enhancement of the abrasion resistance of acrylic resin coating compared to unmodified ZrO2 nanoparticles.