Three-dimensional hybrid networks based on aspartic acid

Abstract

Three-dimensional achiral coordination polymers of the general formula M2(D, L-NHCH (COO)CH2COO)2·C 4H4N2 where M = Ni and Co and pyrazine acts as the linker molecule have been prepared under hydrothermal conditions starting with [M(L-NHCH(COO)CH2COO)·3H2O] possessing a helical chain structure. A three-dimensional hybrid compound of the formula Pb2.5[N{CH(COO) CH2COO}22H2O] has also been prepared hydrothermally starting with aspartic acid and Pb(NO 3)2. In this lead compound, where a secondary amine formed by the dimerisation of aspartic acid acts as the ligand, there is two-dimensiortal inorganic connectivity and one-dimensional organic connectivity. © Indian Academy of Sciences.