Oxidative addition of carbon-fluorine and carbon-oxygen bonds to Al(i)

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Abstract

Addition of fluoroarenes, fluoroalkanes or benzofuran to [{(2,6-iPr2C6H3NCMe)2CH}Al] results in facile oxidative addition of either a C-F or C-O bond to the Al(i) centre.

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Crimmin, M. R., Butler, M. J., & White, A. J. P. (2015). Oxidative addition of carbon-fluorine and carbon-oxygen bonds to Al(i). Chemical Communications, 51(88), 15994–15996. https://doi.org/10.1039/c5cc07140b

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