Microstructure of aluminide coatings modified by Pt, Pd, Zr and Hf formed in low-activity CVD process

Abstract

In the present article the doping of aluminide coatings by Pt/Pd as well as Hf or Pd using industrial processes was developed. The different combinations of doping elements were tested as well as their influence on chemical composition of coatings was initially investigated. The Pt and Pd and both Pt + Pd was electroplated on the surface of the MAR M247 nickel superalloy. The Zr or Hf was doped during low activity CVD aluminizing process using industrial Bernex BPX Pro 325S system. The conducted research showed that Pt and Pd formed the (Ni, Pd, Pt) Al solid solution in the outer additive layer. The higher concentration of palladium in the near surface and in the whole additive layer was detected. The platinum was presented below the surface of aluminide coating. The Zr or Hf was detected mainly in the diffusion zone. The low concentration of Zr (about 0.1 wt.%) in the outer zone was observed. The hafnium was detected mainly in the diffusion zone but in the outer additive layer a small concentration of this element was measured. The obtained results showed that formation of three elements (Pd, Pt) + Zr or Hf modified aluminide coating using proposed technology is possible. The structure of all obtained aluminide coatings was typical for a low-activity, high temperature (LAHT) formation process mainly by outward diffusion of Ni from base material.