Abstract
Monomeric iminoalane: A donor-stabilized monomeric iminoalane was prepared by the reaction of 1 with an N-heterocyclic carbene (see scheme). The X-ray structure exhibits a very short Ali-N bond of 1.705(4) Å, which suggests multiple-bond character. Treatment of the iminoalane with phenyl acetylene, aniline, and carbon monoxide resulted in addition reactions to the formal AlïN bond, thus indicating that the Ali-N multiple bond is highly reactive. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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Li, J., Li, X., Huang, W., Hu, H., Zhang, J., & Cui, C. (2012). Synthesis, structure, and reactivity of a monomeric iminoalane. Chemistry - A European Journal, 18(48), 15263–15266. https://doi.org/10.1002/chem.201203298
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