Specific Features of Using High-Silica Flux Ore in Copper Smelting Units

Abstract

This study explores the application of high-silica flux ore in copper smelting and converting processes at the Zhezkazgan Copper Smelting plant. Pilot-scale experiments and SEM analyses were performed to assess its influence on slag composition, temperature regime, and metal recovery. The results demonstrated that replacing conventional flux with high-silica ore reduced flux consumption by 19%, increased converter slag temperature from 1124 to 1174 °C, and decreased copper content in converter slag from 10% to 4.5%. SEM micro-analysis revealed the formation of lead-containing silicate rims around matte inclusions, which hinder their settling at low temperatures. However, when the slag temperature exceeded 1400 °C, these rims were destroyed, facilitating separation and reducing residual copper. These findings highlight the potential of high-silica fluxes (>90% SiO2) to improve both energy efficiency and metal recovery in process of copper matte converting, offering practical recommendations for industrial operations.