N′-[(1E,2E)-3,7-Dimethyl-octa-2,6-dien-1-yl-idene] pyridine-4-carbohydrazide

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Abstract

In the title compound, C16H21N3O, the mol-ecule adopts an E conformation about the central C=N double bond. The 2-methyl-pent-2-ene group is disordered over two sets of sites, with a refined occupancy ratio of 0.785 (8):0.215 (8). The dihedral angle between the essentially planar [the r.m.s. value for the major component is 0.021 (7) and its maximum deviation is 0.025 (4) Å; the r.m.s. value for the minor component is 0.03 (4) and its maximum deviation is 0.05 (3) Å] major and minor components of the 2-methyl-but-2-ene group is 35.9 (13)°. In the crystal, C-H⋯O and N-H⋯O hydrogen bonds link the molecules, with the same O atom acting as the acceptor. This results in C 1 1(4) and C 1 1(5) [001] chains.

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Bhat, M. A., Abdel-Aziz, H. A., Ghabbour, H. A., Hemamalini, M., & Fun, H. K. (2012). N′-[(1E,2E)-3,7-Dimethyl-octa-2,6-dien-1-yl-idene] pyridine-4-carbohydrazide. Acta Crystallographica Section E: Structure Reports Online, 68(4). https://doi.org/10.1107/S1600536812009075

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