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Difluoromethylation and gem-difluorocyclopropenation with difluorocarbene generated by decarboxylation

Chemical Communications (2015) 51(42) 8805-8808
DOI: 10.1039/c5cc02736e
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Abstract

Difluoromethylation of the activated X-H bond (X = N, O and S) and aliphatic thiols, and gem-difluorocyclopropenation of alkynes with difluorocarbene generated in situ from difluoromethylene phosphobetaine (Ph3P+CF2CO2-) by decarboxylation occurred smoothly without the presence of any base or other additives.

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APA

Deng, X. Y., Lin, J. H., Zheng, J., & Xiao, J. C. (2015). Difluoromethylation and gem-difluorocyclopropenation with difluorocarbene generated by decarboxylation. Chemical Communications, 51(42), 8805–8808. https://doi.org/10.1039/c5cc02736e

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