Vanishing fine structure splitting in highly asymmetric InAs/InP quantum dots without wetting layer

Abstract

Contrary to simplified theoretical models, atomistic calculations presented here reveal that sufficiently large in-plane shape elongation of quantum dots can not only decrease, but even reverse the splitting of the two lowest optically active excitonic states. Such a surprising cancellation of bright-exciton splitting occurs for shape-anisotropic nanostructures with realistic elongation ratios, yet without a wetting layer, which plays here a vital role. However, this non-trivial effect due to shape-elongation is strongly diminished by alloy randomness resulting from intermixing of InAs quantum-dot material with the surrounding InP matrix. Alloying randomizes, and to some degree flattens the shape dependence of fine-structure splitting giving a practical justification for the application of simplified theories. Finally, we find that the dark-exciton spectra are rather weakly affected by alloying and are dominated by the effects of lateral elongation.