NMR evidence for Mott-Hubbard localization

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Abstract

(Formula presented) and (Formula presented) measurements of (Formula presented) unambiguously demonstrated that its magnetic properties are described as a (Formula presented) localized spin system over the entire temperature range (300 K-4.2 K). A possible antiferromagnetic structure that appeared below 45 K is compatible with the orientational order of (Formula presented) pairs on the octahedral (O) site. The present NMR study strongly suggests that the Mott-Hubbard localization occurs due to the removal of the (Formula presented)-orbital degeneracy. © 2000 The American Physical Society.

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Tou, H., Maniwa, Y., Iwasa, Y., Shimoda, H., & Mitani, T. (2000). NMR evidence for Mott-Hubbard localization. Physical Review B - Condensed Matter and Materials Physics, 62(2), R775–R778. https://doi.org/10.1103/PhysRevB.62.R775

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