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Intramolecular alkynylcyclopropanation of olefins catalyzed by Bi(OTf) 3: stereoselective synthesis of 1-alkynyl-3-azabicyclo[3.1.0]hexanes

Angewandte Chemie - International Edition (2009) 48(52)
DOI: 10.1002/anie.200904610
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Abstract

The postman always rings twice: 1Alkynyl-3-azabicyclo[3.1.0]hexanes 2 were obtained in good to excellent yields from the stereoselective Bi(OTf) 3-catalyzed dehydrative alkynylcyclopropanation of azaenynols 1, in which the propargyl alcohol motif of 1 acted as a propargyl carbene synthetic equivalent © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

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Komeyama, K., Saigo, N., Miyagi, M., & Takaki, K. (2009). Intramolecular alkynylcyclopropanation of olefins catalyzed by Bi(OTf) 3: stereoselective synthesis of 1-alkynyl-3-azabicyclo[3.1.0]hexanes. Angewandte Chemie - International Edition, 48(52). https://doi.org/10.1002/anie.200904610

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