Enantioselective epoxidation of styrene derivatives by chloroperoxidase catalysis

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Abstract

Chloroperoxidase catalysed epoxidadon of styrene derivatives by t-BuOOH preferentially gives (R) oxides with ee values between 28 and 68%. The data support the view of oxygen delivery from the ferryl oxygen directly to the substrate. © 1993.

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Colonna, S., Gaggero, N., Casella, L., Carrea, G., & Pasta, P. (1993). Enantioselective epoxidation of styrene derivatives by chloroperoxidase catalysis. Tetrahedron: Asymmetry, 4(6), 1325–1330. https://doi.org/10.1016/S0957-4166(00)80243-8

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