Spontaneous oxidation of water to oxygen by the mixed-valence μ-oxo ruthenium dimer L2(H2O)RuIII-O-Ru IV(OH)L2 (L = 2,2′-bipyridyl-5,5′-dicarboxylic acid)

Mohammad K. Nazeeruddin; François P. Rotzinger; Pascal Comte; Michael Grätzel

Journal Article

Spontaneous oxidation of water to oxygen by the mixed-valence μ-oxo ruthenium dimer L2(H2O)RuIII-O-Ru IV(OH)L2 (L = 2,2′-bipyridyl-5,5′-dicarboxylic acid)

Journal of the Chemical Society, Chemical Communications (1988) (13) 872-874

DOI: 10.1039/C39880000872

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Abstract

The mixed-valence μ-oxo ruthenium dimer L2(H 2O)RuIII-O-RuIV(OH)L2, where L = 2,2′-bipyridyl-5,5′-dicarboxylic acid, converts spontaneously into L2(H2O)RuIII-O-RuIII(H 2O)L2 under simultaneous oxidation of water to oxygen under conditions where the driving force of the reaction is less than 0.1 eV per transferred electron.

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Nazeeruddin, M. K., Rotzinger, F. P., Comte, P., & Grätzel, M. (1988). Spontaneous oxidation of water to oxygen by the mixed-valence μ-oxo ruthenium dimer L2(H2O)RuIII-O-Ru IV(OH)L2 (L = 2,2′-bipyridyl-5,5′-dicarboxylic acid). Journal of the Chemical Society, Chemical Communications, (13), 872–874. https://doi.org/10.1039/C39880000872

Spontaneous oxidation of water to oxygen by the mixed-valence μ-oxo ruthenium dimer L2(H2O)RuIII-O-Ru IV(OH)L2 (L = 2,2′-bipyridyl-5,5′-dicarboxylic acid)

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