Electrodeposition of Continuous Silicon Coatings from the KF-KCl-K 2 SiF 6 Melts

  • Zhuk S
  • Isakov A
  • Apisarov A
  • et al.
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Abstract

The silicon electrodeposition from the KF-KCl-(10 mol%) K2SiF6 melt at 943–1103 K has been studied. The polycrystalline continuous single-phase silicon coatings (∼99.9 wt% Si) have been obtained on the graphite, glassy carbon, silver, and tungsten substrates. The Raman spectroscopic study of the Si/C and Si/Ag interfaces has proved an absence of the intermediate phases. Two phases (Si and Ni2Si) were formed during the silicon electrodeposition on nickel.

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Zhuk, S. I., Isakov, A. V., Apisarov, A. P., Grishenkova, O. V., Isaev, V. A., Vovkotrub, E. G., & Zaykov, Y. P. (2017). Electrodeposition of Continuous Silicon Coatings from the KF-KCl-K 2 SiF 6 Melts. Journal of The Electrochemical Society, 164(8), H5135–H5138. https://doi.org/10.1149/2.0171708jes

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