Effect of sintering parameters on the dynamic hysteresis scaling behavior of Ba0.85Sr0.15Zr0.1Ti0.9O3 ceramics

Abstract

This article presents the effect of processing parameters on the ferroelectric hysteresis behavior of Ba0.85Sr0.15Zr0.1Ti0.9O3 (BSZT) ceramics. The ferroelectric hysteresis scaling relations for coercive field (Ec) and remnant polarization (Pr) as a function of temperature have been proposed. The power law temperature exponents based on scaling were systematically established for all the hysteresis parameters. The temperature dependent scaling of Ec and Pr at sintering temperature of 1400, 1425, 1450 and 1475°C yields EcαT0.43, EcαT0.84, EcαT0.50, EcαT0.37 and PrαT−1.73, PrαT−1.55, PrαT−1.73, PrαT−1.69 respectively. Additionally, the scaling relations for the samples sintered at 1450°C at different time intervals of 3, 4, 5 and 6 hrs were also established. Finally, to understand the domain dynamics, back switching polarization (Pbc) as a function of temperature (T) was also estimated by Arrhenius law and the average activation energy was evaluated.