Enantio-Enriched CPL-active helicene-bipyridine-rhenium complexes

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Abstract

The incorporation of a rhenium atom within an extended helical π-conjugated bi-pyridine system impacts the chiroptical and photophysical properties of the resulting neutral or cationic complexes, leading to the first examples of rhenium-based phosphors that exhibit circularly polarized luminescence.

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Saleh, N., Srebro, M., Reynaldo, T., Vanthuyne, N., Toupet, L., Chang, V. Y., … Crassous, J. (2015). Enantio-Enriched CPL-active helicene-bipyridine-rhenium complexes. Chemical Communications, 51(18), 3754–3757. https://doi.org/10.1039/c5cc00453e

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