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Total synthesis of bacilosarcins A and B

Angewandte Chemie - International Edition (2009) 48(6) 1144-1148
DOI: 10.1002/anie.200804571
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Abstract

(Chemical Equation Presented) I want to ride my bicycle: The thermodynamic stability of nitrogen-containing heterocyclic ring systems is exploited in the first enantioselective total synthesis of bacilosarcins A and B, which has been achieved in simple two-step sequences from amicoumacin C. Bacilosarcin A incorporates a totally unprecedented heterobicyclic ring system and exhibits a remarkably potent herbicidal activity. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

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Enomoto, M., & Kuwahara, S. (2009). Total synthesis of bacilosarcins A and B. Angewandte Chemie - International Edition, 48(6), 1144–1148. https://doi.org/10.1002/anie.200804571

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