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Remote rearrangement of the metal center in a (η6-C6Me6)Ru(ii) complex

Chemical Communications (2015) 51(24) 4981-4984
DOI: 10.1039/c4cc09699a
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Abstract

Reaction of [(η6-C6Me6)RuCl(Ph)(PMe3)] with internal alkynes in the presence of NaBArF4 gave rise to the 1,4-Ru migration to form the o-vinylaryl complex, providing the first example of 1,4-metal migration of a group 8 metal center; in one case further isomerization to an η3-allyl complex was observed.

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Takano, K., Ikeda, Y., Kodama, S., & Ishii, Y. (2015). Remote rearrangement of the metal center in a (η6-C6Me6)Ru(ii) complex. Chemical Communications, 51(24), 4981–4984. https://doi.org/10.1039/c4cc09699a

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