Cinchona alkaloid-metal complexes: Noncovalent porous materials with unique gas separation properties

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Abstract

Pores for thought: Dinuclear aluminum-cinchone complexes are used to construct chiral architectures through noncovalent-interaction-driven self-assembly (see picture). The flexible desolvated material with ultramicropores is a selective adsorbent with unique properties, such as temperature-triggered adsorption of N2 and high affinities for H2, CO2, and CH4. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA.

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Lewiński, J., Kaczorowski, T., Prochowicz, D., Lipińska, T., Justyniak, I., Kaszkur, Z., & Lipkowski, J. (2010). Cinchona alkaloid-metal complexes: Noncovalent porous materials with unique gas separation properties. Angewandte Chemie - International Edition, 49(39), 7035–7039. https://doi.org/10.1002/anie.201002925

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