Synthesis of nano CoAl2O4 pigment for ink-jet printing to decorate porcelain

Abstract

The CoAl2O4 pigment commonly used for coloring ceramic products was synthesized by microwave hydrothermal processing (M-H), and ink-jet printing with this aqueous pigment ink was performed to decorate porcelain. First, a precursor was prepared by adjusting the solution to pH 12. Then, M-H reaction was applied to this precursor at 240°C for 2 h, yielding particles of CoAl2O4. In addition, the precursor concentration of the suspension was shown to greatly affect the color tone of the resulting particles. As the precursor concentration increased, the synthesized particles that were bluish-green at lower concentrations took on a darker blue color. The synthesized CoAl2O4 particles were regular octahedrons measuring approximately 70 nm. The particles synthesized by M-H reaction were used to prepare an aqueous suspension, which was then used for printing on tiles by an ink-jet printing system. The synthesized particles were well dispersed in the prepared aqueous suspension, as little sediment was formed in this suspension left for 1 week. The printing system experienced no clogging and the printed image was of good quality. © 2011 The Ceramic Society of Japan.