Abstract
Integrated but separate: A strongly nucleophilic cluster surface allows the selective complexation and separation of ammonium and potassium ions. Six {Mo4VKO6} rings with crown-ether-like functionality (see picture; Mo blue, V green, K pink, O red) present in the holes of the investigated cluster complex integrate six ammonium ions (N orange, H yellow). © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.
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Müller, A., Sousa, F. L., Merca, A., Bögge, H., Miró, P., Fernández, J. A., … Bo, C. (2009). Supramolecular chemistry on a cluster surface: Fixation/complexation of potassium and ammonium ions with crown-ether-like rings. Angewandte Chemie - International Edition, 48(32), 5934–5937. https://doi.org/10.1002/anie.200902137
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