Synthesis of linear monodisperse vinylene-linked phenothiazine oligomers

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Abstract

A series of linear monodisperse vinylene-linked phenothiazine oligomers have been synthesized by alternate Heck reaction and Wittig reaction in good yields. It was found that their absorption and fluorescence emission bands red-shifted with increasing phenothiazine units due to extending of the conjugated degree. The fluorescent quantum yield increased from OPTZ1 to OPTZ6, and the ΦF of OPTZ6 was close to phenothiazine-based polymers. © 2007 Elsevier Ltd. All rights reserved.

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Qiu, X., Lu, R., Zhou, H., Zhang, X., Xu, T., Liu, X., & Zhao, Y. (2007). Synthesis of linear monodisperse vinylene-linked phenothiazine oligomers. Tetrahedron Letters, 48(43), 7582–7585. https://doi.org/10.1016/j.tetlet.2007.09.002

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