The Cosmic Dust Analyzer: Experimental Evaluation of an Impact Ionization Model

Abstract

Determination of the elemental composition of cosmic dust particles by means of an impact ionization time-of-flight mass spectrometer has been investigated at several institutions. In most configurations, the instrument supplies the identity of ion groups of both target and particle materials extracted from the impact plasma and the number of ions contained in each group. Experiments have shown that the fractional ionization of a given species is not constant with impact velocity nor is the fractional ionization the same for different kinds of atoms. A model of the impact ionization effect developed at TRW involves an equilibrium plasma condition with the consequence that the fractional ionization for an arbitrary atomic species can be specified by the Saha equation if the plasma volume (V) and temperature (T) are known. It follows that T can be determined by taking the ratio of the Saha equations for two elements present in the target in known concentration. (Taking the ratio negates the requirement of knowing V.) Given T, the procedure can be reversed to yield the relative abundance of elements contained in the impacting particle. To test the model, a PbZrO 3 -PbTiO 3 target was bombarded with high velocity Fe, MoB, and NiAl particles and the number of Pb, Ti, and Zr ions was determined in a time-of-flight mass spectrometer. For each event, the relative abundance of Ti to Pb was taken as known (from electron microprobe analysis) and T was determined from the Ti-Pb measurement. The Zr to Pb ratio was found to be in good agreement with the microprobe analysis (0.38 calculated mean value compared to 0.34 actual). The result was valid for all particle materials and for a velocity range 17