Abstract
An efficient synthesis of racemic methylenecyclopropaneacetic acid has been developed. A mixture of the corresponding diastereomeric coenzyme A esters, one of which is the metabolite of the nonprotein amino acid hypoglycin from Blighia sapida directly responsible for its hypoglycemic potency, reacts stereospecifically with general acyl-CoA dehydrogenase from pig kidney to irreversibly inactivate the enzyme. © 1987, American Chemical Society. All rights reserved.
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CITATION STYLE
Baldwin, J. E., & Parker, D. W. (1987). Stereospecific (Methylenecyclopropyl)acetyl-CoA Inactivation of General Acyl-CoA Dehydrogenase from Pig Kidney. Journal of Organic Chemistry, 52(8), 1475–1477. https://doi.org/10.1021/jo00384a017
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