Order-disorder behavior in the ferroelectric nematic phase investigated via Raman spectroscopy

Abstract

Polar-ordered fluids are of interest both fundamentally and from an application standpoint. The recently discovered ferroelectric nematic phase is an example of a polar-ordered fluid, and while there has been extensive research interest in these materials, some of the fundamental properties are yet to be fully understood. Here, we report the order parameters of one of the first known materials that exhibit a ferroelectric nematic phase, RM734, determined via Raman spectroscopy. Raman spectroscopy been used extensively to determined order parameters in liquid crystals systems but also to probe ferroelectric behavior in solid ferroelectric systems and is therefore a powerful technique to study the ferroelectric nematic phase. A reduction and subsequent recovery of order parameters (Δ(P2)≈0.1, Δ(P4)≈0.06) is observed near the onset of the N to NF transition, a feature that is confirmed via complementary birefringence measurements. This dip in order parameters has been attributed to splay fluctuations, which occur at the onset of the NF transition; here we suggest a different explanation. A broadening of the full-width half-maxima (FWHM), of the order of 1 cm-1, of the selected Raman peak is observed near the N to NF phase transition, which we relate to either a change in reorientational dynamics or the onset of polar order. The NF transition is analyzed using standard solid ferroelectric frameworks. An energetic barrier associated with the para- to ferroelectric transition is found to be of the order of 2.5±0.6kJ/mol, which is comparable to solid ferroelectric materials.