Effect of surface coating on optical properties of Eu3+-doped CaMoO4 nanoparticles

Abstract

A simple polyol method has been used for the synthesis of CaMoO 4:Eu (core), CaMoO4:Eu@CaMoO4 (core/shell) and their silica coated CaMoO4:Eu@CaMoO4 (core/shell/shell) nanoparticles. X-ray diffraction (XRD), thermo-gravimetric analysis (TGA), Fourier transform Raman (FT-Raman), Fourier transform infrared (FT-IR), UV/Vis absorption and photoluminescence (PL) spectroscopies techniques has been employed for their characterization. XRD patterns and FT-Raman spectra showed that these nanoparticles have a scheelite-type tetragonal structure without the presence of deleterious phases. These nanoparticles were easily dispersed in water, producing a transparent colloidal solution. The optical energy band-gap decreases after core/shell formation due to increase the crystalline size. The photoluminescence (PL) spectra of the as-synthesized core, core/shell and core/shell/shell nanoparticles measured with an excitation source wavelength of 325 nm showed that the emission intensity was increases after shell formation around the surface of core nanoparticles. © 2014 Elsevier B.V. All rights reserved.