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Biomimetic synthesis via polyepoxide cyclizations

Pure and Applied Chemistry (2007) 79(2) 281-291
DOI: 10.1351/pac200779020281
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Abstract

The biomimetic synthesis of trans,syn,trans-fused polycyclic ether natural products involving a cascade of stereospecific and regioselective oxacyclizations of polyepoxide substrates is described as applied to the synthesis of polyoxepane and polypyran structures. In addition, an extension of biomimetic polyene cyclizations to terpenoid natural products is outlined. © 2007 IUPAC.

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McDonald, F. E., Tong, R., Valentine, J. C., & Bravo, F. (2007). Biomimetic synthesis via polyepoxide cyclizations. In Pure and Applied Chemistry (Vol. 79, pp. 281–291). https://doi.org/10.1351/pac200779020281

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